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Sodium metavanadate: Difference between revisions

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<sup>−</sup> units, each sharing two corners]] <sup>−</sup> units, each sharing two corners]]


'''Sodium metavanadate''' is the ] with the formula NaVO<sub>3</sub>.<ref>{{cite journal|last1=Kato|first1= K.|last2= Takayama|first2= E. |title=Das Entwässerungsverhalten des Natriummetavanadatdihydrats und die Kristallstruktur des beta-Natriummetavanadats|trans-title=The dehydration activity of sodium metavanadate dihydrate and the crystal structure of β-sodium metavanadate|journal=]|date= 1984 |volume =B40 |issue= 2|pages=102–105|doi=10.1107/S0108768184001828}}</ref> It is a yellow, water-soluble salt. '''Sodium metavanadate''' is the ] with the formula NaVO<sub>3</sub>.<ref>{{cite journal|last1=Kato|first1= K.|last2= Takayama|first2= E. |title=Das Entwässerungsverhalten des Natriummetavanadatdihydrats und die Kristallstruktur des beta-Natriummetavanadats|trans-title=The dehydration activity of sodium metavanadate dihydrate and the crystal structure of β-sodium metavanadate|journal=]|date= 1984 |volume =B40 |issue= 2|pages=102–105|doi=10.1107/S0108768184001828|bibcode= 1984AcCrB..40..102K}}</ref> It is a yellow, water-soluble salt.


Sodium metavanadate is a common precursor to other vanadates. At low pH it converts to sodium ]. It is also precursor to exotic metalates such as <sup>5-</sup>, <sup>4-</sup>, and <sup>5-</sup>.<ref>{{cite journal |doi=10.1002/9780470132586.ch17|title=Vanadium(V) Substituted Dodecatungstophosphates|journal=Inorganic Syntheses|year=2007|last1=Domaille|first1=Peter J.|pages=96–104|isbn=9780470132586}}</ref> Sodium metavanadate is a common precursor to other vanadates. At low pH it converts to sodium ]. It is also precursor to exotic metalates such as <sup>5-</sup>, <sup>4-</sup>, and <sup>5-</sup>.<ref>{{cite book |doi=10.1002/9780470132586.ch17|chapter=Vanadium(V) Substituted Dodecatungstophosphates|year=2007|last1=Domaille|first1=Peter J.|title=Inorganic Syntheses |volume=27 |pages=96–104|isbn=9780470132586}}</ref>


==Minerals== ==Minerals==

Latest revision as of 14:14, 24 January 2024

Sodium metavanadate
Names
IUPAC name Sodium trioxovanadate(V)
Identifiers
CAS Number
3D model (JSmol)
ChEBI
ECHA InfoCard 100.033.869 Edit this at Wikidata
EC Number
  • 237-272-7
PubChem CID
RTECS number
  • YW1050000
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/Na.3O.V/q+1;;;-1;
SMILES
  • (=O)=O.
Properties
Chemical formula NaVO3
Molar mass 121.9295 g/mol
Appearance yellow crystalline solid
Density 2.84g/cm
Melting point 630 °C (1,166 °F; 903 K)
Solubility in water 19.3 g/100 mL (20 °C)
40.8 g/100 mL (80 °C)
Thermochemistry
Heat capacity (C) 97.6 J/mol K
Std molar
entropy (S298) 		113.8 J/mol K
Std enthalpy of
formation (ΔfH298) 		−1148 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Toxic, irritant
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2 0 0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose) 98 mg/kg (rat, oral)
Related compounds
Other anions Sodium orthovanadate
Other cations Ammonium metavanadate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒N verify (what is  ?) Infobox references
Chemical compound
Chain of tetrahedral vanadate units, each sharing two corners

Sodium metavanadate is the inorganic compound with the formula NaVO3. It is a yellow, water-soluble salt.

Sodium metavanadate is a common precursor to other vanadates. At low pH it converts to sodium decavanadate. It is also precursor to exotic metalates such as , , and .

Minerals

Sodium metavanadate occurs as two minor minerals, metamunirite (anhydrous) and a dihydrate, munirite. Both are very rare, metamunirite is now known only from vanadium- and uranium-bearing sandstone formations of central-western USA and munirite from Pakistan and South Africa.

References

  1. Kato, K.; Takayama, E. (1984). "Das Entwässerungsverhalten des Natriummetavanadatdihydrats und die Kristallstruktur des beta-Natriummetavanadats" [The dehydration activity of sodium metavanadate dihydrate and the crystal structure of β-sodium metavanadate]. Acta Crystallogr. B40 (2): 102–105. Bibcode:1984AcCrB..40..102K. doi:10.1107/S0108768184001828.
  2. Domaille, Peter J. (2007). "Vanadium(V) Substituted Dodecatungstophosphates". Inorganic Syntheses. Vol. 27. pp. 96–104. doi:10.1002/9780470132586.ch17. ISBN 9780470132586.
  3. "Munirite". Mindat.
Sodium compounds
Inorganic
Halides
Chalcogenides
Pnictogenides
Oxyhalides
Oxychalcogenides
Oxypnictogenides
Others
Organic


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