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Hexamethylene triperoxide diamine

Names
Preferred IUPAC name 3,4,8,9,12,13-Hexaoxa-1,6-diazabicyclotetradecane
Identifiers
CAS Number	283-66-9
3D model (JSmol)	Interactive image
ChEMBL	ChEMBL346085
ChemSpider	55052
PubChem CID	61101
CompTox Dashboard (EPA)	DTXSID9074804
InChI InChI=1S/C6H12N2O6/c1-7-2-11-13-5-8(4-10-9-1)6-14-12-3-7/h1-6H2Key: HMWPNDNFTFSCEB-UHFFFAOYSA-N InChI=1/C6H12N2O6/c1-7-2-11-13-5-8(4-10-9-1)6-14-12-3-7/h1-6H2Key: HMWPNDNFTFSCEB-UHFFFAOYAC
SMILES C1N2COOCN(COO1)COOC2
Properties
Chemical formula	C6H12N2O6
Molar mass	208.17 g/mol
Appearance	White crystalline solid
Density	1.57 g/cm
Melting point	Decomposes at 75 °C Ignites spontaneously at 133 °C
Hazards
Occupational safety and health (OHS/OSH):
Main hazards	Explosive
GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H202, H205, H241, H300, H315, H318, H335
Precautionary statements	P102, P220, P243, P250, P261, P264, P280, P283, P370+P380, P372, P404
NFPA 704 (fire diamond)	1 1 4
Explosive data
Shock sensitivity	High
Friction sensitivity	Very High
Detonation velocity	~2800 m/s (at around 0.4 g/cm) - 5100 m/s at around 1.1 g/cm
RE factor	0.74
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Y verify (what is  ?) Infobox references

Hexamethylene triperoxide diamine (HMTD) is a high explosive organic compound. HMTD is an organic peroxide, a heterocyclic compound with a cage-like structure. It is a primary explosive. It has been considered as an initiating explosive for blasting caps in the early part of 20th century, mostly because of its high initiating power (higher than that of mercury fulminate) and its inexpensive production. As such, it was quickly taken up as a primary explosive in mining applications. However, it has since been superseded by more (chemically) stable compounds such as dextrinated lead azide and DDNP (which contains no lead or mercury). HMTD is widely used in amateur-made blasting caps.

Preparation and structure

First synthesised in 1885 by the German chemist Ludwig Legler, HMTD may be prepared by the reaction of an aqueous solution of hydrogen peroxide and hexamine in the presence of an acid catalyst, such as citric acid, acetic acid or dilute sulfuric acid. The hydrogen peroxide needs to be at least 12% w/w concentration, as lower concentrations lead to poor yields. Citric acid is overall superior to other acids, providing a yield of up to about 50%.

The molecule adopts a cage-like structure with the nitrogen atoms having an unusual trigonal planar geometry.

Properties as an explosive

Like other organic peroxides, such as acetone peroxide (TATP), HMTD is unstable and detonated by shock, friction, static electricity discharges, concentrated sulfuric acid, strong UV radiation and heat. Cases of detonation caused by the simple act of screwing a lid on a jar containing HMTD have been reported. Common static electricity discharges have been reported to cause detonation. It is, however, less unstable than many other peroxides under normal conditions; exposure to ultraviolet light increases its sensitivity. It also reacts with most common metals, which can lead to detonation. HMTD is chemically very stable when pure (free of acids, bases, and metal ions) and does not quickly sublime like its acetone counterparts.

HMTD is a more powerful initiating explosive than mercury fulminate, but its poor thermal and chemical stability prevents its use in detonators. Nevertheless, HMTD is one of the three most widely used primary explosives in improvised, amateur made blasting caps, the others being TATP and silver acetylide.

HMTD is a common source of injury, particularly finger amputations, among amateur chemists. Most of these injuries are caused by small amounts of HMTD that inadvertently detonate in close proximity of fingers, since small amounts (grams) are generally not powerful enough to amputate fingers from distances larger than 5 – 10 cm.

Calculated (Explo5) detonation pressure P_cj at crystal density 1.597 g/cm is 218 kbar with velocity of detonation VoD = 7777 m/s. Explosion temperature is 3141 K, energy of explosion is 5612 kJ/kg (or 3400 - 4000 kJ/kg per various sources) and volume of explosion gases at STP is calculated to be 826 L/kg. Loose powder has density close to 0.4 g/cm, hence the common detonation velocities are closer to 3000 m/s and P_cj is closer to 15 kbar.

Sensitivity

HMTD is overall slightly more sensitive than fresh TATP and can be considered to be slightly more dangerous than an average primary explosive. The variance of friction force between different surfaces (e.g. different kinds of paper) is often greater than the variance between the friction sensitivity of a given pair of primary explosives. This leads to different values for friction sensitivity measured at different laboratories.

Terrorism

Despite no longer being used in any military application, and despite its shock sensitivity, HMTD remains a common home-made explosive and has been used in a large number of suicide bombings and other attacks throughout the world. For example, it was one of the components in the explosives intended to bomb Los Angeles International Airport in the 2000 millennium attack plots and the 2016 New York and New Jersey bombings, as well as one of the components of the explosives attempted to be made by the neo-Nazi terrorist organization Atomwaffen Division in the United States.

References

1. Taylor, C. A.; Rinkenbach, W. H. Army Ordnance 1924. 5, 463–466
2. Legler, L. (1885). "Ueber Producte der langsamen Verbrennung des Aethyläthers". Berichte der Deutschen Chemischen Gesellschaft. 18 (2): 3343–3351. doi:10.1002/cber.188501802306.
3. Schaefer, William P.; Fourkas, John T.; Tiemann, Bruce G. (April 1985). "Structure of hexamethylene triperoxide diamine". Journal of the American Chemical Society. 107 (8): 2461–2463. Bibcode:1985JAChS.107.2461S. doi:10.1021/ja00294a043.
4. Stúpajúci trend podomáckej výroby výbušnin a udalosti s tým spojené, Kriminalistický a expertízny ústav Policajného zboru, p. 8 http://www.unms.sk/swift_data/source/dokumenty/skusobnictvo/upravy_2009/odborne_seminare_2008/KEU_BA_01_10_2008.pdf Archived 23 September 2021 at the Wayback Machine, written in Slovak
5. Explosive Properties of Primary Explosives - Springer, p.21, section 2.33, ISBN 978-3-642-28436-6, https://www.springer.com/cda/content/document/cda_downloaddocument/9783642284359-c1.pdf?SGWID=0-0-45-1379807-p174306459 Archived 21 July 2018 at the Wayback Machine
6. Hodgson, Robert; Agrawal, Jai P. (2007). Organic Chemistry of Explosives. Wiley. p. 414.
7. Stúpajúci trend podomáckej výroby výbušnin a udalosti s tým spojené, Kriminalistický a expertízny ústav Policajného zboru, p. 8 http://www.unms.sk/swift_data/source/dokumenty/skusobnictvo/upravy_2009/odborne_seminare_2008/KEU_BA_01_10_2008.pdf Archived 23 September 2021 at the Wayback Machine, written in Slovak
8. The Chemistry of Peroxides. John Wiley & Sons. 2015. ISBN 9781118412718.
9. U.S. Court of Appeals for the Ninth Circuit (2 February 2010). "U.S. v. Ressam" (PDF). Archived from the original (PDF) on 4 October 2012. Retrieved 27 February 2010.
10. "Complaint; U.S. v. Ressam" (PDF). NEFA Foundation. December 1999. Archived from the original (PDF) on 1 March 2012. Retrieved 26 February 2010.
11. Cullinane, Susannah; Shimon Prokupecz; Emanuella Grinberg; Holly Yan (20 September 2016). "7 questions we have about bombings in New York and New Jersey". CNN. Retrieved 20 September 2016.
12. Thompson, A.C. (20 November 2018). Documenting Hate: New American Nazis. Frontline. PBS/ProPublica. 15 minutes in. Retrieved 19 February 2019.

• Organic peroxides
• Explosive chemicals
• Diamines
• Organic peroxide explosives