Trifluoromethylisocyanide: Difference between revisions

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	{{chembox		{{chembox
			\| Verifiedfields = changed
	\| verifiedrevid = ~~402697107~~		\| verifiedrevid = 470614562
	\| ImageFile = Trifluoromethyl isocyanide.svg		\| ImageFile = Trifluoromethyl isocyanide.svg
	\| ImageSize = 160		\| ImageSize = 160
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	\| IUPACName = trifluoro(isocyano)methane		\| IUPACName = trifluoro(isocyano)methane
	\| OtherNames = trifluoro-methyl-azaniumylidyne methane		\| OtherNames = trifluoro-methyl-azaniumylidyne methane
	\| Section1 = {{Chembox Identifiers		\|Section1={{Chembox Identifiers
	\| InChI = 1/C2F3N/c1-6-2(3,4)5		\| InChI = 1/C2F3N/c1-6-2(3,4)5
	\| InChIKey = LKHQVUSYAMWNQZ-UHFFFAOYAU		\| InChIKey = LKHQVUSYAMWNQZ-UHFFFAOYAU
	\| StdInChI_Ref = {{stdinchicite\|correct\|chemspider}}		\| StdInChI_Ref = {{stdinchicite\|correct\|chemspider}}
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	\| StdInChIKey_Ref = {{stdinchicite\|correct\|chemspider}}		\| StdInChIKey_Ref = {{stdinchicite\|correct\|chemspider}}
	\| StdInChIKey = LKHQVUSYAMWNQZ-UHFFFAOYSA-N		\| StdInChIKey = LKHQVUSYAMWNQZ-UHFFFAOYSA-N
			\| CASNo_Ref = {{cascite\|correct\|CAS}}
	\| CASNo = 105879-13-8
	\| ~~PubChem~~ = ~~145434~~		\| CASNo = 19480-01-4
	\| ~~ChemSpiderID_Ref~~ = {{~~chemspidercite~~\|correct\|~~chemspider~~}}		\| UNII_Ref = {{fdacite\|correct\|FDA}}
			\| UNII = R3NG676YU8
			\| PubChem = 145434
			\| ChemSpiderID_Ref = {{chemspidercite\|correct\|chemspider}}
	\| ChemSpiderID = 128288		\| ChemSpiderID = 128288
	\| SMILES = #C(F)(F)F		\| SMILES = #C(F)(F)F
	}}		}}
	\| Section2 = {{Chembox Properties		\|Section2={{Chembox Properties
	\| Formula = CF<sub>3</sub>NC		\| Formula = CF<sub>3</sub>NC
	\| MolarMass = 95.023		\| MolarMass = 95.023
	\| Appearance =		\| Appearance =
	\| Density =		\| Density =
	\| MeltingPt =		\| MeltingPt =
	\| BoilingPt =		\| BoilingPt =
	\| Solubility =		\| Solubility =
	}}		}}
	\| Section3 = {{Chembox Hazards		\|Section3={{Chembox Hazards
	\| MainHazards =		\| MainHazards =
	\| FlashPt =		\| FlashPt =
	\| ~~Autoignition~~ =		\| AutoignitionPt =
	}}		}}
	}}		}}

	'''Trifluoromethylisocyanide''' is the chemical compound with the formula CF<sub>3</sub>NC. It is an ] and a ]. Polymerisation occurs even at temperatures below its boiling point of ~~-80~~°C. As a ] in ], this species behaves similarly to ].<ref>{{cite journal\| author=D. Lentz\|title= Fluorinated Isocyanides - More than Ligands with Unusual Properties \|journal= Angewandte Chemie International. Edition English\|year= 1994\|volume= 33\| issue=13\|pages= 1315–1331\| doi=10.1002/anie.199413151}}</ref>		'''Trifluoromethylisocyanide''' is the chemical compound with the formula CF<sub>3</sub>NC. It is an ] and a ]. Polymerisation occurs even at temperatures below its boiling point of −80 °C. As a ] in ], this species behaves similarly to ].<ref>{{cite journal\| author=D. Lentz\|title= Fluorinated Isocyanides - More than Ligands with Unusual Properties \|journal= Angewandte Chemie International Edition in English\|year= 1994\|volume= 33\| issue=13\|pages= 1315–1331\| doi=10.1002/anie.199413151}}</ref>

	The compound ] (CF<sub>3</sub>CN) is an isomer to trifluoromethylisocyanide. The ] is more stable, as is the usual case.		The compound ] (CF<sub>3</sub>CN) is an isomer to trifluoromethylisocyanide. The ] is more stable, as is the usual case.

	==References==		==References==
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	]		]
	]		]

	]
	]
	]

Latest revision as of 01:13, 24 July 2023

Trifluoromethylisocyanide
Names


IUPAC name trifluoro(isocyano)methane
Other names trifluoro-methyl-azaniumylidyne methane
Identifiers
CAS Number	19480-01-4
3D model (JSmol)	Interactive image
ChemSpider	128288
PubChem CID	145434
UNII	R3NG676YU8
CompTox Dashboard (EPA)	DTXSID10147379
InChI InChI=1S/C2F3N/c1-6-2(3,4)5Key: LKHQVUSYAMWNQZ-UHFFFAOYSA-N InChI=1/C2F3N/c1-6-2(3,4)5Key: LKHQVUSYAMWNQZ-UHFFFAOYAU
SMILES #C(F)(F)F
Properties
Chemical formula	CF₃NC
Molar mass	95.023
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). N verify (what is ?) Infobox references

Chemical compound

Trifluoromethylisocyanide is the chemical compound with the formula CF₃NC. It is an isocyanide and a fluorocarbon. Polymerisation occurs even at temperatures below its boiling point of −80 °C. As a ligand in coordination chemistry, this species behaves similarly to carbon monoxide.

The compound trifluoracetonitrile (CF₃CN) is an isomer to trifluoromethylisocyanide. The nitrile is more stable, as is the usual case.

References

D. Lentz (1994). "Fluorinated Isocyanides - More than Ligands with Unusual Properties". Angewandte Chemie International Edition in English. 33 (13): 1315–1331. doi:10.1002/anie.199413151.

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