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Dichloro(cycloocta-1,5-diene)platinum(II): Difference between revisions

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'''Dichloro(1,5-cyclooctadiene)platinum(II)''' ('''Pt(cod)Cl<sub>2</sub>''') is an ] of ]. This colourless solid, which is a commercially available, is an entry point to other platinum compounds through the displacement of the cod and/or chloride ]s. It is prepared from ] and the diene.<ref>{{cite journal | author = E. Costa, P. G. Pringle, M. Ravetz | title = Dimethyl-Platinum(II)| journal = ] | year = 1997 | volume = 31 | pages = 284–286 | doi = 10.1002/9780470132623.ch49}}</ref> '''Dichloro(1,5-cyclooctadiene)platinum(II)''' ('''Pt(cod)Cl<sub>2</sub>''') is an ] of ]. This colourless solid, which is a commercially available, is an entry point to other platinum compounds through the displacement of the cod and/or chloride ]s. It is prepared from ] and the diene.<ref>{{cite journal | author = E. Costa, P. G. Pringle, M. Ravetz | title = Dimethyl-Platinum(II)| journal = ] | year = 1997 | volume = 31 | pages = 284–286 | doi = 10.1002/9780470132623.ch49 | series = Inorganic Syntheses | isbn = 9780470132623}}</ref>


==References== ==References==

Revision as of 11:38, 21 October 2011

Dichloro(cycloocta-1,5-diene)platinum(II)
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.937 Edit this at Wikidata
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;Key: VVAOPCKKNIUEEU-PHFPKPIQSA-L
  • InChI=1/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;Key: VVAOPCKKNIUEEU-AUZMAREFBX
SMILES
  • ClCl.C\1=C\CC/C=C\CC/1
Properties
Chemical formula C8H12Cl2Pt
Molar mass 374.17 g·mol
Melting point 285 °C (545 °F; 558 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkY verify (what is  ?) Infobox references
Chemical compound

Dichloro(1,5-cyclooctadiene)platinum(II) (Pt(cod)Cl2) is an organometallic compound of platinum. This colourless solid, which is a commercially available, is an entry point to other platinum compounds through the displacement of the cod and/or chloride ligands. It is prepared from potassium tetrachloroplatinate and the diene.

References

  1. E. Costa, P. G. Pringle, M. Ravetz (1997). "Dimethyl-Platinum(II)". Inorg. Synth. Inorganic Syntheses. 31: 284–286. doi:10.1002/9780470132623.ch49. ISBN 9780470132623.{{cite journal}}: CS1 maint: multiple names: authors list (link)

Further reading

  • Ashfaquzzaman Syed, Edwin D. Stevens, Sandra G. Cruz (1984). "Reexamination of the π bonding in dichloro(cycloocta-1,5-diene)platinum". Inorg. Chem. 23 (22): 3673–3674. doi:10.1021/ic00190a053.{{cite journal}}: CS1 maint: multiple names: authors list (link)
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