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4-Nitrothiophenol: Difference between revisions

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Revision as of 03:24, 19 January 2025

4-Nitrothiophenol
Identifiers
CAS Number
ECHA InfoCard 100.015.852 Edit this at Wikidata
CompTox Dashboard (EPA)
Properties
Chemical formula C6H5NO2S
Molar mass 155.17 g·mol
Appearance yellow solid
Density 1.362 g/cm
Melting point 79–80 °C (174–176 °F; 352–353 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

4-Nitrothiophenol is an organosulfur compound with the formula HSC6H4NO2. It exists as a yellow solid that is soluble in several organic solvent]]s. The compound is one of three isomers of nitrothiophenol. It was originally prepared by sulfidation of 4-nitrochlorobenzene.

The compound reacts with chlorine to give 4-nitrophenylsulfenyl chloride, a useful reagent. It has also been used as a probe of plasmon-induced reactions.

References

  1. Fromm, E.; Wittmann, J. (1908). "Derivate des p -Nitrothiophenols". Berichte der Deutschen Chemischen Gesellschaft. 41 (2): 2264–2273. doi:10.1002/cber.190804102131.
  2. Kim, Sunggak (2007). "4-Nitrobenzenesulfenyl Chloride". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/9780470842898.rn00720. ISBN 978-0-471-93623-7.
  3. Sun, Mengtao; Xu, Hongxing (2012). "A Novel Application of Plasmonics: Plasmon-Driven Surface-Catalyzed Reactions". Small. 8 (18): 2777–2786. doi:10.1002/smll.201200572. PMID 22777813.
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