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Revision as of 14:38, 21 January 2025
Names | |
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IUPAC name azanium;periodate | |
Other names Ammonium tetraoxoiodate(VII) | |
Identifiers | |
CAS Number | |
3D model (JSmol) | |
PubChem CID | |
CompTox Dashboard (EPA) | |
InChI
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SMILES
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Properties | |
Chemical formula | H4INO4 |
Molar mass | 208.939 g·mol |
Appearance | colorless crystals |
Density | 3.056 g/cm |
Solubility in water | soluble |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references |
Ammonium periodate is a chemical compound with the chemical formula NH4IO4.
Synthesis
Ammonium periodate is formed by the reaction between periodic acid and ammonia:
- HIO4 + NH4OH → NH4IO4 + H2O
Physical properties
The compound forms colorless crystals of tetragonal system, spatial group I41/a, cell parameters a = 0.5938 nm, c = 1.2790 nm, Z = 4.
It is soluble in water. Explodes when heated.
References
- Rezende, Armando de; Pantoya, Michelle L.; Tunega, Daniel; Aquino, Adelia J. A. (8 February 2024). "Prediction of Phase Transition and Ignition Sensitivity of Ammonium Periodate". The Journal of Physical Chemistry C. 128 (5): 2205–2214. doi:10.1021/acs.jpcc.3c07439. ISSN 1932-7447. Retrieved 21 January 2025.
- Rao, Chintamani Nagesa Ramachandra (1975). Bibliography of Infrared Spectroscopy Through 1960. U.S. Department of Commerce, National Bureau of Standards. p. 1929. Retrieved 21 January 2025.
- EPA-600/2. Industrial Environmental Research Laboratory, Office of Research and Development, U.S. Environmental Protection Agency. 1980. p. 78. Retrieved 21 January 2025.