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Revision as of 15:57, 16 February 2012 editBeetstra (talk | contribs)Edit filter managers, Administrators172,074 edits Saving copy of the {{chembox}} taken from revid 468904592 of page 1,1,1,2-Tetrachloroethane for the Chem/Drugbox validation project (updated: 'CASNo').  Latest revision as of 17:58, 26 April 2024 edit Marbletan (talk | contribs)Extended confirmed users5,615 editsmNo edit summary 
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{{short description|Chemical compound}}
{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}}
{{chembox {{chembox
| Verifiedfields = changed
| verifiedrevid = 443239599
| Watchedfields = changed
| Reference = <ref></ref>
| verifiedrevid = 477201350
| Reference = <ref>{{Cite web |url=http://www.npi.gov.au/database/substance-info/profiles/79.html |title=National Pollutant Inventory Substance Profile |access-date=2007-07-19 |archive-url=https://web.archive.org/web/20070829044828/http://www.npi.gov.au/database/substance-info/profiles/79.html |archive-date=2007-08-29 |url-status=dead }}</ref>
| ImageFileL1 = 1,1,1,2-Tetrachloroethane.svg | ImageFileL1 = 1,1,1,2-Tetrachloroethane.svg
| ImageSizeL1 = 120px | ImageSizeL1 = 120px
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| ImageSizeR1 = 120px | ImageSizeR1 = 120px
| ImageNameR1 = Ball-and-stick model of 1,1,1,2-tetrachloroethane | ImageNameR1 = Ball-and-stick model of 1,1,1,2-tetrachloroethane
| IUPACName = 1,1,1,2-Tetrachloroethane | PIN = 1,1,1,2-Tetrachloroethane
| OtherNames = R-130a | OtherNames = R-130a; acetylidene tetrachloride, asymmetrical tetrachloroethane
| Section1 = {{Chembox Identifiers |Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChEBI_Ref = {{ebicite|correct|EBI}} | ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 34024 | ChEBI = 34024
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = QVLAWKAXOMEXPM-UHFFFAOYSA-N | StdInChIKey = QVLAWKAXOMEXPM-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|??}} | CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = <!-- blanked - oldvalue: 630-20-6 --> | CASNo = 630-20-6
| UNII_Ref = {{fdacite|correct|FDA}}
| PubChem = 12418
| UNII = 0S5MKE574X
| SMILES = C(C(Cl)(Cl)Cl)Cl
| PubChem = 12418
| SMILES = C(C(Cl)(Cl)Cl)Cl
}} }}
| Section2 = {{Chembox Properties |Section2={{Chembox Properties
| C=2|H=2|Cl=4 | C=2 | H=2 | Cl=4
| Appearance = Clear liquid
| MolarMass = 167.848 g/mol
| Density = 1.5532 g/cm{{sup|3}}
| Appearance = Clear liquid
| MeltingPtC = -70.2
| Density = 1.5532 g/cm<sup>3</sup>
| MeltingPtC = -70.2 | BoilingPtC = 130.5
| Solubility = 0.1% (20°C)<ref name=PGCH/>
| BoilingPtC = 130.5
| VaporPressure = 14 mmHg (25°C)<ref name=PGCH/>
| Solubility =
}} }}
| Section3 = {{Chembox Hazards |Section3={{Chembox Hazards
| MainHazards = | MainHazards =
| FlashPt = | FlashPt =
| Autoignition = | AutoignitionPt =
| IDLH = N.D.<ref name=PGCH>{{PGCH|0597}}</ref>
| REL = Handle with caution in the workplace.<ref name=PGCH/>
| PEL = none<ref name=PGCH/>
}} }}
}} }}

'''1,1,1,2-Tetrachloroethane''' is a ]. It is a colorless liquid with a sweet ]-like odor. It is used as a ] and in the production of ]s and ]es. It is an isomer of ].

==Production==
1,1,1,2-Tetrachloroethane can be obtained by a two-step addition reaction of ] with chlorine (via ]), but this mainly produces 1,1,2,2-tetrachloroethane.

:{{chem2 | C2H2 + Cl2 -> C2H2Cl2 }}

:{{chem2 | C2H2Cl2 + Cl2 -> C2H2Cl4 }}

It can be obtained directly by chlorination of ]:<ref>Lawrance Waddams: ''The Petroleum chemicals Industry'', S.&nbsp;175.</ref>

:{{chem2 | CHCl2\sCH2Cl + Cl2 -> CCl3\sCH2Cl + HCl }}

==Safety==
] has classified 1,1,1,2-tetrachloroethane as a possible carcinogen for humans in 2014.<ref></ref>

== See also==
* ]

==References==
<references/>

{{DEFAULTSORT:Tetrachlorethane, 1, 1, 1, 2-}}
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]
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