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Revision as of 13:30, 3 January 2011 editChemLlama (talk | contribs)Extended confirmed users1,039 edits Add info← Previous edit		Latest revision as of 17:33, 17 June 2024 edit undoSmokefoot (talk | contribs)Autopatrolled, Extended confirmed users, Pending changes reviewers, Rollbackers75,010 edits →Preparation and structure: reformat ref
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	{{chembox		{{Chembox
			| Watchedfields = changed
	| verifiedrevid = 401612975		| verifiedrevid = 405682296
⚫	| Name = Cadmium bromide
	| ImageFile =Cadmium-chloride-3D-balls.png		| Name = Cadmium bromide
			| ImageFile =Cadmium-chloride-3D-balls.png
	| ImageName = Cadmium bromide		| ImageFile2 = Cadmium bromide tetrahydrate.jpg
	| IUPACName = Cadmium(II) bromide		| ImageName = Cadmium bromide
		⚫	| IUPACName = Cadmium(II) bromide
	| Chemical Name = CdBr
	| OtherNames = Cadmium dibromide		| OtherNames = Cadmium dibromide
	| Section1 = {{Chembox Identifiers		|Section1={{Chembox Identifiers
	| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}		| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
	| ChemSpiderID = 23011		| ChemSpiderID = 23011
	| UNII_Ref = {{fdacite|correct|FDA}}		| UNII_Ref = {{fdacite|correct|FDA}}
	| UNII = 7726AXS0WH		| UNII = 7726AXS0WH
			| EINECS = 232-165-1
	| InChI = 1/2BrH.Cd/h2*1H;/q;;+2/p-2		| InChI = 1/2BrH.Cd/h2*1H;/q;;+2/p-2
	| SMILES = BrBr		| SMILES = BrBr
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	| StdInChIKey = KPWJBEFBFLRCLH-UHFFFAOYSA-L		| StdInChIKey = KPWJBEFBFLRCLH-UHFFFAOYSA-L
	| CASNo = 7789-42-6		| CASNo = 7789-42-6
	| CASNo_Ref = {{cascite|correct|CAS}}		| CASNo_Ref = {{cascite|correct|CAS}}
			| CASNo_Comment =
	| CASOther = <br> 13464-92-1 (tetrahydrate)
	| RTECS =		| CASNo2 = 13464-92-1
			| CASNo2_Comment = (tetrahydrate)
			| CASNo2_Ref = {{cascite|correct|CAS}}
			| RTECS = EU9935000
			| PubChem = 24609
	}}		}}
	| Section2 = {{Chembox Properties		|Section2={{Chembox Properties
	| Formula = CdBr<sub>2</sub>		| Formula = CdBr<sub>2</sub>
	| MolarMass = 272.22 g/mol		| MolarMass = 272.22 g/mol
	| Appearance = white to pale yellow crystalline solid		| Appearance = white solid
	| Density = 5.192 g/cm<sup>3</sup>, solid		| Density = 5.192 g/cm<sup>3</sup>, solid
	| Solubility = 56.3 g/100 mL (0 °C) <br> 98.8 g/100 mL (20 °C) <br> 160 g/100 mL (100 °C)		| Solubility = 56.3 g/100 mL (0 °C) <br> 98.8 g/100 mL (20 °C) <br> 160 g/100 mL (100 °C)
	| SolubleOther = soluble in ], ], ] and liquid ].		| SolubleOther = soluble in ], ], ] and liquid ].
	| MeltingPt = 568 °C		| MeltingPtC = 568
			| MeltingPt_notes =
	| BoilingPt = 844 °C
			| BoilingPtC = 844
			| BoilingPt_notes =
			| MagSus = -87.3·10<sup>−6</sup> cm<sup>3</sup>/mol
	}}		}}
	| Section3 = {{Chembox Structure		|Section3={{Chembox Structure
	| CrystalStruct = ], ], SpaceGroup = R-3m, No. 166		| CrystalStruct = ], ], SpaceGroup = R-3m, No. 166
	}}		}}
	| Section7 = {{Chembox Hazards		|Section7={{Chembox Hazards
	| ExternalMSDS =		| ExternalSDS =
			| GHSPictograms = {{GHS07}}{{GHS09}}
	| EUClass = Harmful ('''Xn''')<br/>Dangerous for the environment ('''N''')
			| GHSSignalWord = Warning
	| EUIndex = 048-001-00-5
			| HPhrases = {{H-phrases|302|312|332|410}}
⚫	| NFPA-H = 2
			| PPhrases = {{P-phrases|220|273|280|501}}
⚫	| NFPA-F = 0
	| NFPA-R = 0		| NFPA-H = 3
		⚫	| NFPA-F = 0
	| RPhrases = {{R20/21/22}}, {{R50/53}}
		⚫	| NFPA-R = 0
	| SPhrases = {{S2}}, {{S60}}, {{S61}}
	| LD50 = 225 mg/kg, oral (rat)		| LD50 = 225 mg/kg, oral (rat)
			| REL = Ca<ref name=PGCH>{{PGCH|0087}}</ref>
			| PEL = TWA 0.005 mg/m<sup>3</sup> (as Cd)<ref name=PGCH/>
			| IDLH = Ca <ref name=PGCH/>
	}}		}}
	| Section8 = {{Chembox Related		|Section8={{Chembox Related
	| OtherAnions = ],<br/>]		| OtherAnions = ],<br />]
	| OtherCations = ],<br/>],<br/>]		| OtherCations = ],<br />],<br />]
	}}		}}
	}}		}}
			'''Cadmium bromide''' is the inorganic compound with the formula CdBr<sub>2</sub>. It is a white hygroscopic solid. It also can be obtained as a mono- and tetrahydrate.<ref name=Brauer/> It has few applications.
	'''Cadmium bromide''' is a cream-coloured crystalline ionic ] ] of ] that is soluble in water. It is very toxic, along with other cadmium compounds.
		⚫	==Preparation and structure==
	==Uses==
			Cadmium bromide is prepared by heating cadmium with bromine vapor.<ref name=Brauer>{{cite book|author1=F. Wagenknecht|author2=R. Juza|chapter=Cadmium bromide|title=Handbook of Preparative Inorganic Chemistry, 2nd Ed. |editor=G. Brauer|publisher=Academic Press|year=1963|place=NY, NY|volume=2|pages=1096}}</ref> The tetrahydrate has been obtained by crystallization of the dibromide from aqueous solution. At 3.04 g/cm<sup>3</sup>, it is much less dense than the anhydrous material. According to ], the tetrahydrate is a polymer of CdBr<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub> with bridging bromide ligands. There are two interstitial water molecules<ref>{{cite journal |doi=10.1107/S0567740878002186 |title=Structure Cristalline de CdBr<sub>2</sub><sup>.</sup>4H<sub>2</sub>O |date=1978 |last1=Leligny |first1=H. |last2=Monier |first2=J. C. |journal=Acta Crystallographica Section B |volume=34 |issue=1 |pages=5–8 |bibcode=1978AcCrB..34....5L }}</ref>
	It is used in the manufacturing of ], ] and ].
⚫	==Preparation==
	Cadmium bromide is prepared by heating cadmium with bromine vapor. Also the compound can be prepared by the treatment of dry ] with glacial ] and ]. Alternatively, it can be obtained by dissolving cadmium or ] in ] and evaporating the solution to dryness under ] in an inert atmosphere.<ref>Pradyot Patnaik. ''Handbook of Inorganic Chemicals''. McGraw-Hill, 2002, ISBN 0070494398</ref>
	==References==		==References==
	<references/>		<references />
	{{Cadmium compounds}}		{{Cadmium compounds}}
			{{bromine compounds}}
	]		]
	]		]
			]
	]		]
	{{inorganic-compound-stub}}		{{inorganic-compound-stub}}
	]
	]
	]
	]
	]
	]
	]