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| verifiedrevid = 372241744 |
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| Name = Platinum(IV) bromide |
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| verifiedrevid = 446972486 |
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| ImageFile = |
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| Name = Platinum(IV) bromide |
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| ImageFile =PtBr4.svg |
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| ImageName = |
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| IUPACName = Platinum(IV) bromide |
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| ImageName = |
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| OtherNames = Platinic bromide |
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| IUPACName = Platinum(IV) bromide |
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| Section1 = {{Chembox Identifiers |
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| OtherNames = Platinic bromide |
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| CASNo = 68936-92-1 |
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|Section1={{Chembox Identifiers |
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| RTECS = |
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| CASNo_Ref = {{cascite|changed|??}} |
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| PubChem = |
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| CASNo = 68938-92-1 |
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| ChemSpiderID = 100307 |
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| PubChem = 111865 |
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| EINECS = 273-151-5 |
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| SMILES = Br(Br)(Br)Br |
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| StdInChI = 1S/4BrH.Pt/h4*1H;/q;;;;+4/p-4 |
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| StdInChIKey = SNPHNDVOPWUNON-UHFFFAOYSA-J |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| Formula = PtBr<sub>4</sub> |
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| Formula = PtBr<sub>4</sub> |
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| MolarMass = 514.700 g/mol |
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| MolarMass = 514.694 g/mol |
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| Appearance = brownish-black crystals |
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| Appearance = brownish-black crystals |
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| Density = |
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| Density = |
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| Solubility = 0.41 g/100mL @ 20°C |
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| Solubility = 0.41 g/100mL @ 20°C |
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| MeltingPt = decomposes at 180°C |
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| MeltingPt = decomposes at 180°C |
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| SolubleOther = slightly soluble in ], ]<ref name="hand"> |
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| SolubleOther = slightly soluble in ], ]<ref name="hand"> |
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{{Citation |
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{{Citation |
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| last = Lide |
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| last = Lide |
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| first = David R. |
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| first = David R. |
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| author-link = |
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| author-link = |
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| last2 = |
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| year = 1998 |
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| title = Handbook of Chemistry and Physics |
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| first2 = |
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| edition = 87 |
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| volume = |
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| publication-date = |
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| date = |
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| location = Boca Raton, Florida |
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| year = 1998 |
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| publisher = CRC Press |
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| title = Handbook of Chemistry and Physics |
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| edition = 87 |
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| id = |
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| isbn = 0-8493-0594-2 |
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| volume = |
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| oclc = |
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| publication-place = Boca Raton, FL |
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| place = |
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| pages = 481 |
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| url = https://books.google.com/books?id=lFjg0L-uOxoC&q=%22Platinum(IV)+bromide%22&pg=PT866 |
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| publisher = CRC Press |
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| access-date = 2008-06-19 |
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| id = |
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| isbn = 0849305942 |
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| doi = |
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| oclc = |
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| pages = 481 |
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| url = http://books.google.com/?id=lFjg0L-uOxoC&pg=PT866&dq=%22Platinum(IV)+bromide%22 |
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| accessdate = 2008-06-19 |
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}}</ref> |
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}}</ref> |
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| BoilingPt = |
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| BoilingPt = |
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| Section3 = {{Chembox Structure |
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|Section3={{Chembox Structure |
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| MolShape = |
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| Coordination = |
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| Coordination = |
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| CrystalStruct = |
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| Dipole = |
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| Section7 = {{Chembox Hazards |
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|Section7={{Chembox Hazards |
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| ExternalMSDS = |
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| ExternalSDS = |
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| NFPA-H = 2 |
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| NFPA-H = 2 |
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| NFPA-F = 0 |
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| NFPA-F = 0 |
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| NFPA-R = 1 |
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| NFPA-R = 1 |
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| GHSPictograms = {{GHS05}} |
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| EUClass = Corrosive ('''C''') |
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| GHSSignalWord = Danger |
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| RPhrases = {{R34}} |
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| HPhrases = {{H-phrases|314}} |
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| SPhrases = {{S20}}, {{S26}}, {{S36/37/39}}, {{S45}}, {{S60}} |
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| PPhrases = {{P-phrases|260|264|280|301+330+331|303+361+353|304+340|305+351+338|310|321|363|405|501}} |
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| FlashPt = non-flammable |
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| FlashPt = non-flammable |
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| Section8 = {{Chembox Related |
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|Section8={{Chembox Related |
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| OtherAnions = ]<br />]<br />] |
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| OtherAnions = ]<br />]<br />] |
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| OtherCations = ]<br />]<br />] |
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| OtherCations = ]<br />] |
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| OtherCompounds = ] |
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'''Platinum(IV) bromide''' is the ] with the ] PtBr<sub>4</sub>. It is a brown solid. It is a little-used compound mainly of interest for academic research.<ref>{{cite journal |doi=10.1021/acs.chemmater.5b01247|title=Effect of Precursor Ligands and Oxidation State in the Synthesis of Bimetallic Nano-Alloys|year=2015|last1=Lagrow|first1=Alec P.|last2=Knudsen|first2=Kristian Rahbek|last3=Alyami|first3=Noktan M.|last4=Anjum|first4=Dalaver H.|last5=Bakr|first5=Osman M.|journal=Chemistry of Materials|volume=27|issue=11|pages=4134–4141|hdl=10754/553018|hdl-access=free}}</ref> It is a component of a reagent used in ].<ref name="reag"> |
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'''Platinum(IV) bromide''' is the ] composed of ] and ] with the ] PtBr<sub>4</sub>. |
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A solution of platinum(IV) bromide and ] in water can be used to test for the presence of ] by putting a drop of the reagent and a drop of the unknown solution onto a piece of ]. A gray or black stain indicates a positive result; however, the mechanism for this reaction is unknown |
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<ref name="reag"> |
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{{Citation |
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{{Citation |
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| last = Wenger |
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| last = Wenger |
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| first = P. E. |
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| first = P. E. |
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| author-link = |
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| author-link = |
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| last2 = |
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| year = 2007 |
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| title = Reagents for Qualitative Inorganic Analysis |
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| first2 = |
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| year = 2007 |
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| location = |
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| title = Reagents for Qualitative Inorganic Analysis |
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| publisher = Read Country Books |
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| edition = |
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| isbn = 978-1-4067-4847-5 |
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| pages = 242 |
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| publisher = Read Country Books |
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| url = https://books.google.com/books?id=SRAR3FOYxhEC&q=%22Platinum(IV)+bromide%22&pg=PA360 |
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| id = |
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| access-date = 2008-06-18 |
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| isbn = 1406748471 |
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}}</ref> |
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In terms of structure, the compound is an inorganic polymer consisting of interconnected PtBr<sub>6</sub> octahedra. |
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| pages = 242 |
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| url = http://books.google.com/?id=SRAR3FOYxhEC&pg=PA360&dq=%22Platinum(IV)+bromide%22 |
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| accessdate = 2008-06-18 |
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}}</ref>. |
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==References== |
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==References== |
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{{reflist}} |
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{{reflist}} |
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{{Platinum compounds}} |
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{{Bromides}} |
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{{inorganic-compound-stub}} |
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{{inorganic-compound-stub}} |
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] |
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] |
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