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Revision as of 14:33, 10 January 2012 editBeetstra (talk | contribs)Edit filter managers, Administrators172,074 edits Saving copy of the {{chembox}} taken from revid 460928091 of page Trost_ligand for the Chem/Drugbox validation project (updated: 'CASNo').		Latest revision as of 18:46, 18 July 2023 edit Fadesga (talk | contribs)Autopatrolled, Extended confirmed users266,976 edits →External links
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	{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}}
	{{chembox		{{chembox
			| Verifiedfields = changed
⚫	| verifiedrevid = 443637426
			| Watchedfields = changed
		⚫	| verifiedrevid = 470618137
	| ImageFile = Trost ligand.png		| ImageFile = Trost ligand.png
	| ImageSize =		| ImageSize =
	| ImageFile1 = Trost-ligand-3D-balls.png		| ImageFile1 = Trost-ligand-from-xtal-1999-Mercury-3D-balls.png
	| IUPACName = (1''R'',2''R'')-(+)-1,2-diaminocyclohexane-''N'',''N'''-bis(2-diphenylphosphinobenzoyl)		| IUPACName = (1''R'',2''R'')-(+)-1,2-diaminocyclohexane-''N'',''N'''-bis(2-diphenylphosphinobenzoyl) {{citation needed|date=July 2023}}
			| PIN = ''N'',''N''′-bis
	| OtherNames = Trost's ligand		| OtherNames = Trost's ligand
	| Section1 = {{Chembox Identifiers		|Section1={{Chembox Identifiers
	| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}		| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
	| ChemSpiderID = 9138733		| ChemSpiderID = 9138733
	| InChI = 1/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m0/s1		| InChI = 1/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m0/s1
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	| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}		| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
	| StdInChIKey = AXMSEDAJMGFTLR-ZAQUEYBZSA-N		| StdInChIKey = AXMSEDAJMGFTLR-ZAQUEYBZSA-N
	| CASNo_Ref = {{cascite|correct|??}}		| CASNo_Ref = {{cascite|changed|??}}
	| CASNo = <!-- blanked - oldvalue: 138517-61-0 -->		| CASNo = 138517-61-0
			| UNII_Ref = {{fdacite|correct|FDA}}
⚫	| PubChem = 10963521
			| UNII = M4RRX95R5F
⚫	| SMILES = O=C(N4CCCC4NC(=O)c3ccccc3P(c1ccccc1)c2ccccc2)c7ccccc7P(c5ccccc5)c6ccccc6
		⚫	| PubChem = 10963521
		⚫	| SMILES = O=C(N4CCCC4NC(=O)c3ccccc3P(c1ccccc1)c2ccccc2)c7ccccc7P(c5ccccc5)c6ccccc6
	}}		}}
	| Section2 = {{Chembox Properties		|Section2={{Chembox Properties
	| Formula = C<sub>44</sub>H<sub>40</sub>N<sub>2</sub>O<sub>2</sub>P<sub>2</sub>		| Formula = C<sub>44</sub>H<sub>40</sub>N<sub>2</sub>O<sub>2</sub>P<sub>2</sub>
	| MolarMass = 690.75 g/mol		| MolarMass = 690.75{{nbsp}}g/mol
	| Appearance = white solid		| Appearance = White solid
	| Density =		| Density =
	| MeltingPt = 136-142 °C		| MeltingPtC = 136 to 142
	| BoilingPt =		| MeltingPt_notes =
			| BoilingPt =
	| Solubility = insoluble; soluble in organic solvents, e.g. ], ], ], ], ], ]		| Solubility = Insoluble; soluble in organic solvents (e.g. ], ]) ], ], ], ]
⚫	}}
⚫	| Section3 = {{Chembox Hazards
⚫	| MainHazards =
⚫	| FlashPt =
	| Autoignition =
	}}		}}
		⚫	|Section3={{Chembox Hazards
		⚫	| MainHazards =
		⚫	| FlashPt =
			| AutoignitionPt =
		⚫	}}
	}}		}}
			The '''Trost ligand''' is a ] used in the ]-] ]. Other ] derived from ] (DACH) have been developed, such as the (''R'',''R'')-DACH-] ligand derived from 2-diphenylphosphino-1-naphthalenecarboxylic acid. Related ] ]-containing ligands derived from other chiral ] and ] have also been developed for applications in ].
			]{{clear|left}}
			== External links ==
			*
			*
			]
			]
			]
			]
			{{organic-compound-stub}}
			{{Catalysis-stub}}