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Acetyl fluoride

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Not to be confused with Actinium fluoride.
Acetyl fluoride
Names
Preferred IUPAC name Acetyl fluoride
Systematic IUPAC name Ethanoyl fluoride
Other names Methylcarbonyl fluoride
Identifiers
CAS Number
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.008.354 Edit this at Wikidata
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • Key: JUCMRTZQCZRJDC-UHFFFAOYSA-N
  • InChI=1S/C2H3FO/c1-2(3)4/h1H3
SMILES
  • FC(=O)C
Properties
Chemical formula C2H3FO
Molar mass 62.043 g·mol
Density 1.032 g/cm
Melting point −84 °C (−119 °F; 189 K)
Boiling point 21 °C (70 °F; 294 K)
Hazards
GHS labelling:
Pictograms GHS05: Corrosive
Signal word Danger
Hazard statements H314
Precautionary statements P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Acetyl fluoride is an acyl halide with the chemical formula CH3COF. The formula is commonly abbreviated AcF. This chemical is corrosive. This chemical can be known as Acetyl fluoride, 557-99-3 or Methylcarbonyl fluouride. It carries a oxo group at position 1.

Synthesis

Acetyl fluoride is synthesized using hydrogen fluoride and acetic anhydride. Acetic acid is produced as a byproduct.

HF + (CH
3CO)
2O → CH
3CO
2H + CH
3COF

See also

References

  1. "Acetyl fluoride". Archived from the original on 2014-03-28. Retrieved 2012-03-07.
  2. "Acetyl Fluoride". NIST. Archived from the original on 21 February 2019. Retrieved 7 March 2012.
  3. PubChem. "Acetyl fluoride". pubchem.ncbi.nlm.nih.gov. Retrieved 2023-11-14.
  4. Tanaka, Mutsuo; Fujiwara, Masahiro; Ando, Hisanori (1995). "Dual Reactivity of the Formyl Cation as an Electrophile and a Bransted Acid in Superacids". Journal of Organic Chemistry. 60 (12): 3846–3850. doi:10.1021/jo00117a041.


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