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Laponite

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Laponite is a synthetic smectite clay that was invented in 1962 by clay scientist Barbara Neumann. Laponite is usually produced as powder. It is a nanomaterial, made up of very small disk-shaped crystals, that is used in multiple industrial applications. Laponite was first marketed by the company Laporte plc, and is currently produced by BYK Additives & Instruments. Laponite is not an approved mineral species, since it is not naturally occurring and it is not produced by geological processes.

Development of laponite

In the first formulation of laponite created by Neumann in 1962, the synthetic clay was determined to be a fluorohectorite, and was produced in the form of discs that were 1 nanometer thick, and with a diameter of 60 to 80 nanometres. This went into mass production in 1964. The mineral structure of the clay gives laponite its particular physical characteristics. It has a structure similar to the smectite group of clay minerals, with a 2:1 layered crystal structure in which two tetrahedral silica sheets lie either side of an octahedral sheet containing magnesium ions.

In 1966, Neumann patented a second formulation of laponite, called 'Laponite RD'. This form was free from fluorine, and has subsequently become the most widely used form of laponite. This form of laponite has an empirical formula of Na0.7[(Si8Mg5.5Li0.3)O20(OH)4].

In later years, Neumann also created other variants of laponite including a lithium-free magnesium silicate clay, a form of synthetic stevensite, and an iron silicate clay, which was a synthetic form of nontronite.

References

  1. GB 1054111, Neumann, B.S., "Improvements in or Relating to Synthetic Clay-Like Minerals" 
  2. Neumann, B.S. (1965). "Behaviour of a synthetic clay in pigment dispersions". Rheologica Acta. 4 (4): 250–255. Bibcode:1965AcRhe...4..250N. doi:10.1007/BF01973660.
  3. Brunchi, C.-E.; Morariu, S. (2024). "Laponite—From Dispersion to Gel—Structure, Properties, and Applications". Molecules. 29 (2823): 2823. doi:10.3390/molecules29122823. PMC 11206873. PMID 38930887.
  4. Shafran, Kirill; Jeans, Christopher V; Kemp, Simon J; Murphy, Kevin (2021). "Dr Barbara S. Neumann: Clay Scientist, Industrial Pioneer, Creator of Laponite". Elements. 17 (1): 69–70. Bibcode:2021Eleme..17...69S. doi:10.2138/gselements.17.1.69.
  5. ^ Tomás, Helena; Alves, Carla S.; Rodrigues, João (2018). "Laponite®: A key nanoplatform for biomedical applications?". Nanomedicine: Nanotechnology, Biology and Medicine. 14 (7): 2407–2420. doi:10.1016/j.nano.2017.04.016. PMID 28552649.
  6. "Laponite". mindat.org.
  7. ^ Shafran, Kirill; Jeans, Christopher V; Kemp, Simon J; Murphy, Kevin (2020). "Dr Barbara S. Neumann: Clay Scientist and Industrial Pioneer". Clay Minerals. 55: 256–260. doi:10.1180/clm.2020.35.
  8. GB 1213122, Neumann, B.S., "Clays" 
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