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Strontium oxalate

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Strontium oxalate
Names
IUPAC name Strontium oxalate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.011.286 Edit this at Wikidata
EC Number
  • 212-415-6
PubChem CID
UNII
CompTox Dashboard (EPA)
SMILES
  • .C(=O)C()=O
Properties
Chemical formula SrC2O4
Molar mass 175.64 g·mol
Appearance White powder
Density 2.08 g/cm
Boiling point Decomposes above 200 °C (392 °F; 473 K)
Solubility in water Insoluble in water
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Skin and eye irritant. Inhaling the compound irritates mucous membrane in the lungs.
GHS labelling:
Pictograms GHS07: Exclamation mark
Signal word Warning
Hazard statements H302, H312
Precautionary statements P264, P270, P280, P301+P317, P302+P352, P317, P321, P330, P362+P364, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
1 0 1
Safety data sheet (SDS)
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Strontium oxalate is a compound with the chemical formula SrC2O4. Strontium oxalate can exist either in a hydrated form (SrC2O4·nH2O) or as the acidic salt of strontium oxalate (SrC2O4·mH2C2O4·nH2O). Strontium oxalate is soluble in 20 000 parts of water; in 1 900 parts of 3.5% acetic acid, in 115 parts of the 23% acid, but less soluble in the 35% acid; readily soluble in diluted HCl or nitric acid.

Use in pyrotechnics

With the addition of heat, strontium oxalate will decompose based on the following reaction:

SrC2O4 → SrO + CO2 + CO

Strontium oxalate is a good agent for use in pyrotechnics since it decomposes readily with the addition of heat. When it decomposes into strontium oxide, it produces a red flame color. Since this reaction produces carbon monoxide, which can undergo a further reduction with magnesium oxide, strontium oxalate is an excellent red flame color producing agent in the presence of magnesium. If it is not in the presence of magnesium, strontium carbonate has been found to be a better option to produce an even greater effect.

References

  1. "Strontium oxalate".
  2. Knaepen, E. "Preparation and Thermal Decomposition of Various Forms of Strontium Oxalate". Thermochimica Acta 284.1 (1996): 213-27.
  3. O’Neil, M. J. (Ed.). (2013). The Merck index: An encyclopedia of chemicals, drugs, and biologicals (15a ed.). Royal Society of Chemistry.
  4. Kosanke, K. "Chemical Components of Fireworks Compositions". Pyrotechnic Chemistry. Whitewater, CO: Journal of Pyrotechnics, 2004. 1-11.
Strontium compounds
Compounds of the oxalate ion
(H2C2O4) He
Li2C2O4 BeC2O4 +BO3 +CO3 (NH4)2C2O4
+NO3
O F Ne
Na2C2O4
NaHC2O4
MgC2O4 Al Si +PO4
+PO3
+SO4 +Cl Ar
K2C2O4
KHC2O4
CaC2O4 Sc Ti V CrC2O4 MnC2O4 FeC2O4
Fe2(C2O4)3
+Fe
humboldtine
+NH4 +Na +K +K
CoC2O4 -Ni CuC2O4 Katsarosite Ga2(C2O4)3 Ge As Se Br Kr
Rb2C2O4 SrC2O4 Y2(C2O4)3 Zr Nb(HC2O4)5 Mo Tc Ru Rh Pd Ag2C2O4 CdC2O4 In2(C2O4)3 SnC2O4 Sb Te I Xe
Cs2C2O4 BaC2O4 * Lu2(C2O4)3 Hf Ta W Re Os Ir -Pt Au Hg Tl PbC2O4 Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La2(C2O4)3 Ce2(C2O4)3 Pr2(C2O4)3 Nd2(C2O4)3 Pm2(C2O4)3 Sm2(C2O4)3 Eu2(C2O4)3 Gd2(C2O4)3 Tb2(C2O4)3 Dy2(C2O4)3 Ho2(C2O4)3 Er2(C2O4)3 Tm2(C2O4)3 Yb2(C2O4)3
** Ac2(C2O4)3 Th(C2O4)2 Pa UO2C2O4 Np(C2O4)2 Pu(C2O4)2 Am Cm2(C2O4)3 Bk2(C2O4)3 Cf2(C2O4)3 Es2(C2O4)3 Fm Md No
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